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Journal Articles

Process evaluation of use of High Temperature Gas-cooled Reactors to an ironmaking system based on Active Carbon Recycling Energy System

Hayashi, Kentaro*; Kasahara, Seiji; Kurihara, Kohei*; Nakagaki, Takao*; Yan, X.; Inagaki, Yoshiyuki; Ogawa, Masuro

ISIJ International, 55(2), p.348 - 358, 2015/02

 Times Cited Count:8 Percentile:39.68(Metallurgy & Metallurgical Engineering)

Reducing coking coal consumption and CO$$_{2}$$ emissions by application of iACRES (ironmaking system based on active carbon recycling energy system) was investigated using process flow modeling to show effectiveness of HTGRs (high temperature gas-cooled reactors) adoption to iACRES. Two systems were evaluated: a SOEC (solid oxide electrolysis cell) system using CO$$_{2}$$ electrolysis and a RWGS (reverse water-gas shift reaction) system using RWGS reaction with H$$_{2}$$ produced by IS (iodine-sulfur) process. Both the effects on saving of the coking coal and reduction of CO$$_{2}$$ emissions were greater in the RWGS system. It was the reason of the result that excess H$$_{2}$$ which was not consumed in the RWGS reaction was used as reducing agent in the BF as well as CO. Heat balance in the HTGR, SOEC and RWGS modules were evaluated to clarify process components to be improved. Optimization of the SOEC temperature was desired to reduce Joule heat input for high efficiency operation of the SOEC system. Higher H$$_{2}$$ production thermal efficiency in the IS process for the RWGS system is effective for more efficient HTGR heat utilization. The SOEC system was able to utilize HTGR heat to reduce CO$$_{2}$$ emissions more efficiently by comparing CO$$_{2}$$ emissions reduction per unit heat of HTGR.

Journal Articles

Quantitative evaluation of CO$$_{2}$$ emission reduction of active carbon recycling energy system for ironmaking by modeling with Aspen Plus

Suzuki, Katsuki*; Hayashi, Kentaro*; Kurihara, Kohei*; Nakagaki, Takao*; Kasahara, Seiji

ISIJ International, 55(2), p.340 - 347, 2015/02

 Times Cited Count:19 Percentile:64.17(Metallurgy & Metallurgical Engineering)

Use of the Active Carbon Recycling Energy System in ironmaking (iACRES) has been proposed for reducing CO$$_{2}$$ emissions. To evaluate the performance of iACRES quantitatively, a process flow diagram of a blast furnace model with iACRES was developed using Aspen Plus, a chemical process simulator. CO$$_{2}$$ emission reduction and exergy analysis were performed by using mass and energy balance obtained from simulation results. The following CO$$_{2}$$ reduction methods were evaluated as iACRES: solid oxide electrolysis cells (SOEC) with CO$$_{2}$$ capture and separation (CCS), SOEC without CCS, and a reverse water-gas shift reactor powered by a high-temperature gas-cooled reactor. iACRES enabled CO$$_{2}$$ emission reduction by 3-11% by recycling CO and H$$_{2}$$, whereas effective exergy ratio decreased by 1-7%.

Journal Articles

Process modeling of iACRES by ASPEN Plus and evaluation of the whole system

Hayashi, Kentaro*; Suzuki, Katsuki*; Kurihara, Kohei*; Nakagaki, Takao*; Kasahara, Seiji

Tanso Junkan Seitetsu Kenkyukai Saika Hokokusho; Tanso Junkan Seitetsu No Tenkai, p.27 - 41, 2015/02

Applying Active Carbon Recycling Energy System to ironmaking (iACRES) process is a promising technology to reduce coal usage and CO$$_{2}$$ emissions. To evaluate performance of iACRES quantitatively, a process flow diagram of the blast furnace model with iACRES was developed using Aspen Plus. CO$$_{2}$$ emission reduction and exergy analysis was predicted by using mass and energy balance obtained from the simulation results. The followings were investigated as iACRES: solid oxide electrolysis cells (SOEC) with CO$$_{2}$$ capture and separation (CCS), SOEC without CCS, and a reverse water-gas shift reactor as the a CO$$_{2}$$ reduction reactor powered by a high-temperature gas-cooled reactor. iACRES could provide CO$$_{2}$$ emission reductions of 3-11% by recycling CO and H$$_{2}$$, whereas the effective exergy ratio decreased by 1-7%.

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